{"id":6817,"date":"2023-02-14T14:00:35","date_gmt":"2023-02-14T05:00:35","guid":{"rendered":"https:\/\/www.imass.nagoya-u.ac.jp\/?p=6817"},"modified":"2023-05-22T18:11:18","modified_gmt":"2023-05-22T09:11:18","slug":"20230214_osada","status":"publish","type":"post","link":"https:\/\/www.imass.nagoya-u.ac.jp\/en\/research\/20230214_osada.html","title":{"rendered":"Creation of thinnest freestanding film with ferroelectric properties ever opens the door to smaller, more efficient devices"},"content":{"rendered":"<p><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/www.imass.nagoya-u.ac.jp\/wp\/wp-content\/uploads\/2023\/02\/press-Release-osada_3.png\" alt=\"\" width=\"800\" height=\"661\" class=\"aligncenter size-full wp-image-6923\" srcset=\"https:\/\/www.imass.nagoya-u.ac.jp\/wp\/wp-content\/uploads\/2023\/02\/press-Release-osada_3.png 800w, https:\/\/www.imass.nagoya-u.ac.jp\/wp\/wp-content\/uploads\/2023\/02\/press-Release-osada_3-300x248.png 300w, https:\/\/www.imass.nagoya-u.ac.jp\/wp\/wp-content\/uploads\/2023\/02\/press-Release-osada_3-768x635.png 768w\" sizes=\"auto, (max-width: 800px) 100vw, 800px\" \/><\/p>\r\n<p>&nbsp;<\/p>\r\n<table style=\"width: 75%; border-collapse: collapse; border-style: none;\" class=\" aligncenter\">\r\n<tbody>\r\n<tr>\r\n<td style=\"width: 100%;\">\r\n<p><span style=\"font-size: 20px;\">Researchers at the Institute for Future Materials and Systems at Nagoya University in Japan have successfully synthesized barium titanate (BaTiO<sub>3<\/sub>) nanosheets with a thickness of 1.8 nanometers, the thinnest thickness ever created for a free-standing film. Given that thickness is related to functionality, their findings open the door to smaller, more efficient devices. The research was published in the journal <em>Advanced Electronic Materials<\/em>.<\/span><\/p>\r\n<p><span style=\"font-size: 20px;\">The development of ever-thinner materials with new electronic functions is a highly competitive area of research. Such devices are especially important in ferroelectrics, materials that have a polarization that can be reversed by an electric field. This ability to reverse polarization makes these materials useful in memory and vibrational power generation.<\/span><\/p>\r\n<p><span style=\"font-size: 20px;\">However, as the materials used in these devices become smaller, they exhibit unexpected properties that complicate their industrial use. A big problem is the \"size effect\", as when the material\u2019s thickness is reduced to a few nanometers, its ferroelectric properties disappear.<\/span><\/p>\r\n<p><span style=\"font-size: 20px;\">Now, a team from Nagoya University\u2019s Department of Materials Chemistry and the Institute of Materials and Systems for Sustainability (IMaSS), led by Professor Minoru Osada (he\/him), has successfully synthesized defect-free BaTiO<sub>3<\/sub> nanosheets with ferroelectric properties at a thickness of 1.8 nm using an aqueous solution process. The result is the thinnest free-standing film ever made. Although thin, the film exhibits ferroelectric properties, representing an important breakthrough in the fabrication of thin, ferroelectrically active films.<\/span><\/p>\r\n<p><span style=\"font-size: 20px;\">\u201cHowever, for BaTiO<sub>3<\/sub>, a typical ferroelectric material, it is difficult to synthesize nanosheets by the conventional synthetic method. Therefore, it was necessary to develop a new synthetic method,\u201d Osada said. \u201cGenerally, the synthesis of BaTiO<sub>3<\/sub> requires a calcination process that requires temperatures of 1000\u00b0C or higher. In contrast, we synthesized BaTiO<sub>3<\/sub> nanosheets at a low temperature of 60\u00b0C using our process. Since the thickness of the film can be controlled using this method by varying the reaction time, the synthesis of nanosheets with two to six lattices was achieved.\u201d<\/span><\/p>\r\n<p><span style=\"font-size: 20px;\">\u201cIf nanosheets with a thickness of a few nanometers can be synthesized in ferroelectrics, new properties and applications are expected to be discovered. Our findings should provide an important technique for the miniaturization of devices such as memories and capacitors,\u201d he continued. \u201cAs existing technologies have already reached their limits both in terms of both materials and processes, techniques such as ours are essential. They offer a dramatic increase in performance and technological innovation by the means of new materials and processes.\u201d<\/span><\/p>\r\n<p><span style=\"font-size: 20px;\">The study, \"Molecularly Thin BaTiO<sub>3<\/sub> Nanosheets with Stable Ferroelectric Response,\" has been published in the journal <em>Advanced Electronic Materials<\/em> at DOI: <a href=\"http:\/\/dx.doi.org\/10.1002\/aelm.202201239\">10.1002\/aelm.202201239<\/a><\/span><\/p>\r\n<p><span style=\"font-size: 20px;\"><br><strong>Authors:<\/strong><\/span><\/p>\r\n<p><span style=\"font-size: 20px;\">Kazuki Hagiwara, Ki Nam Byun, Shu Morita, <a href=\"https:\/\/profs.provost.nagoya-u.ac.jp\/html\/100010162_en.html\">Eisuke Yamamoto<\/a>, <a href=\"https:\/\/profs.provost.nagoya-u.ac.jp\/html\/100010247_en.html\">Makoto Kobayashi<\/a>, Xiaoyan Liu, and <a href=\"https:\/\/profs.provost.nagoya-u.ac.jp\/html\/100010020_en.html\">Minoru Osada<\/a><\/span><\/p>\r\n<p><span style=\"font-size: 20px;\"><br><strong>Media Contact:<\/strong><\/span><\/p>\r\n<p><span style=\"font-size: 20px;\">Matthew Coslett<br><\/span><span style=\"font-size: 20px;\">International Communications Office, Nagoya University<br><\/span><span style=\"font-size: 20px;\">kouho-en@adm.nagoya-u.ac.jp<\/span><\/p>\r\n<\/td>\r\n<\/tr>\r\n<\/tbody>\r\n<\/table>","protected":false},"excerpt":{"rendered":"<p>&nbsp; Researchers at the Institute for Future Materials and Systems at Nagoya University in Japan have succes [&hellip;]<\/p>\n","protected":false},"author":4,"featured_media":6923,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"footnotes":""},"categories":[2],"tags":[253,239,251,254,241,242,240],"class_list":["post-6817","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-research","tag-253","tag-239","tag-251","tag-254","tag-241","tag-242","tag-240"],"acf":[],"aioseo_notices":[],"publishpress_future_action":{"enabled":false,"date":"2026-05-07 04:38:20","action":"change-status","newStatus":"draft","terms":[],"taxonomy":"category","extraData":[]},"publishpress_future_workflow_manual_trigger":{"enabledWorkflows":[]},"_links":{"self":[{"href":"https:\/\/www.imass.nagoya-u.ac.jp\/en\/wp-json\/wp\/v2\/posts\/6817","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.imass.nagoya-u.ac.jp\/en\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.imass.nagoya-u.ac.jp\/en\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.imass.nagoya-u.ac.jp\/en\/wp-json\/wp\/v2\/users\/4"}],"replies":[{"embeddable":true,"href":"https:\/\/www.imass.nagoya-u.ac.jp\/en\/wp-json\/wp\/v2\/comments?post=6817"}],"version-history":[{"count":100,"href":"https:\/\/www.imass.nagoya-u.ac.jp\/en\/wp-json\/wp\/v2\/posts\/6817\/revisions"}],"predecessor-version":[{"id":6903,"href":"https:\/\/www.imass.nagoya-u.ac.jp\/en\/wp-json\/wp\/v2\/posts\/6817\/revisions\/6903"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.imass.nagoya-u.ac.jp\/en\/wp-json\/wp\/v2\/media\/6923"}],"wp:attachment":[{"href":"https:\/\/www.imass.nagoya-u.ac.jp\/en\/wp-json\/wp\/v2\/media?parent=6817"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.imass.nagoya-u.ac.jp\/en\/wp-json\/wp\/v2\/categories?post=6817"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.imass.nagoya-u.ac.jp\/en\/wp-json\/wp\/v2\/tags?post=6817"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}